Hierarchical structured α-Al2O3 supported S-promoted Fe catalysts for direct conversion of syngas to lower olefins.
نویسندگان
چکیده
Hierarchical structured α-Al2O3 is shown to be able to effectively disperse and immobilize iron species, in comparison with commercial α-Al2O3. After promotion using an appropriate amount of sulfur, iron catalysts exhibit not only enhanced Fischer-Tropsch synthesis activity and selectivity toward lower olefins, but also increased resistance against carbon deposits.
منابع مشابه
KCl Promoted Cobalt-iron Nanocatalysts Supported on Silica: Catalytic Performance and Characterization in Fischer-Tropsch Synthesis
The SiO2 supported cobalt-iron nano catalysts were prepared by the sol-gel method. This research investigated the effects of (Co/Fe) wt.%, different Co/Fe ratio at different temperature and loading of KCl wt.% for Fisher-Tropsch synthesis (FTS). The results were showed that the catalyst containing 50 wt.% (Co/Fe)/SiO2 (Co/Fe ratio is 70/30) which promoted with 0.6 wt.% KCl is an optimal nano ca...
متن کاملMethane oxy-steam reforming over a highly efficient Ni/Al2O3 nanocatalyst prepared by microwave-assisted impregnation method
An alumina-supported nickel catalyst was prepared by impregnation of Ni2+ solution onto mesoporous alumina under microwave irradiation (denoted as M-Ni/Al2O3). For comparison, a catalyst with the same nickel content was prepared by conventional impregnation method (denoted as UM-Ni/Al2O3). Both M-Ni/Al2O3 and UM-Ni/Al2O3 catalysts were applied to the syngas (H2 + CO) production by methane oxy-s...
متن کاملNa Promoted Ni/γ-Al2O3 Catalysts Prepared by Solution Combustion Method for Syngas Methanation
Ni-based catalysts with different amounts of Na as promoter from 2 to 6 wt % were prepared by solution combustion method. The catalytic activity was investigated in syngas methanation reaction. Carbon oxides conversion and methane selectivity are greatly influenced by sodium loading. Adding 2 wt% Na remarkably improves catalytic activity and long-term stability, attributed to its smaller mean N...
متن کاملThe Effects of Potassium Promoter on the Syngas Conversion of Cobalt Catalysts (TECHNICAL NOTE)
The effects of potassium promoter for production of heavy hydrocarbons from syngas with silica- supported cobalt catalysts has been studied. After preparing the catalysts in accordance with the sol-gel method, they were subjected to various tests by using a small steely micro-reactor and capable of operating in diversified situations, such as stable temperature range, flow rate, space velocity,...
متن کاملEffect of Structural Promoters on Fe-Based Fischer–Tropsch Synthesis of Biomass Derived Syngas
Biomass gasification and subsequent conversion of this syngas to liquid hydrocarbons using Fischer– Tropsch (F–T) synthesis is a promising source of hydrocarbon fuels. However, biomass-derived syngas is different from syngas obtained from other sources such as steam reforming of methane. Specifically the H2/CO ratio is less than 1/1 and the CO2 concentrations are somewhat higher. Here, we repor...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 51 42 شماره
صفحات -
تاریخ انتشار 2015